Department of Chemistry

Research Group Title Organic Polymers and their Composites Research Group (OPCRG)
Area of Research Synthesis of organic polymer and their composites, Catalysis, Adsorption
Theme of Research / Goals Atom transfer radical polymerization, MOFs, COFs, polymeric composites, crosslinked polymers, Catalysis
Faculty Members Dr. Muhammad Arif, Dr. Toheed Akhtar, Dr. Shumaila Razzak
Collaborating UMT Departments Department of Life Sciences
Department of Mathematics
Collaborating National Institutes Department of Chemistry, QAU, Islamabad.
School of Chemistry, University of the Punjab, Lahore.
Department of Chemistry and CASE-EN, NUST, Islamabad.
Collaborating International Institutes KIAST, South Korea.
UNIST, South Korea.
Gachon University, South Korea.
Seoul National University, South Korea.
Polish Academy of Sciences, Poland.
Names of Active Senior Students Muhammad Maqbool, Muhammad Asif Iqbal, Sadia Ashraf, Miss Kainat
Short Description of the Research Theme Organic photoredox catalyzed atom transfer radical polymerization (O-ATRP) is a polymerization technique that uses a photoredox catalyst to control the polymerization process. In ATRP, a radical initiator is used to initiate the polymerization process, and a transition metal catalyst is used to control the polymerization. In O-ATRP, a photoredox catalyst is used instead of a transition metal catalyst to initiate the polymerization process. The photoredox catalyst is excited by light, which then undergoes a single electron transfer process to reduce an initiator to form a radical species that initiates the polymerization. The use of a photoredox catalyst allows for an efficient and environmentally friendly polymerization process, as it eliminates the need for a transition metal catalyst, which can be toxic and expensive. Additionally, organic photoredox catalyzed ATRP offers greater control over the polymerization process, allowing for the synthesis of well-defined polymers with controlled molecular weight and low dispersity.
SDGs Covered Good Health and Well-being (SDG #3), Clean Water and Sanitation (SDG #6), Affordable and Clean Energy (SDG #7), Industry, Innovation and Infrastructure (SDG #9), Climate Action (SDG #13).
List of 5 Relevant Publications Arif, M., Raza, H., Haroon, S. M., Moussa, S. B., Tahir, F., & Alzahrani, A. Y. A. (2024) Silica@poly(chitosan-N-isopropylacrylamide-methacrylic acid) microgels: Extraction of palladium (II) ions and in situ formation of palladium nanoparticles for pollutant reduction
Catalytic reduction of nitroarenes by palladium nanoparticles decorated silica@poly(chitosan-N-isopropylacrylamide-methacrylic acid) hybrid microgels
Arif, M., Javed, M. and Akhter, T., (2024) Crosslinked polymeric networks of TiO 2–polymer composites: a comprehensive review
Arif, M., Raza, H. and Akhter, T., (2024) UV-Vis spectroscopy in the characterization and applications of smart microgels and metal nanoparticle-decorated smart microgels: a critical review
Arif, M., Raza, H., Tahir, F., Moussa, S.B., Haroon, S.M., Alzahrani, A.Y.A. and Akhter, T., (2024) Stabilized Ag nanoparticles loaded smart poly (chitosan-N-isopropylacrylamide-methacrylic acid) hybrid microgels for catalytic reduction of nitroarenes

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